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When reactions are fast relative to the mixing rate, not only are the reaction rates affected but the entire time and temperature history of the reactions is affected, yielding different selectivities and yields depending on the intensity of the mixing This leads to the scale-up problem, where yields of desirable products in a plant scale reactor are not as good as in the small scale reactor in the laboratory or the pilot plant If the yield is poorer in the plant scale reactor, there is a mixing problem, assuming that other important variables are held constant, such as temperature, pressure, and composition.

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The competition between reaction and mixing is well represented by a mixing Damkoehler number, DaM , which is the ratio between the reaction rate and the local mixing rate, or conversely, the ratio of the characteristic mixing time, M , and the reaction time, R : M DaM = (13-4) R A smaller DaM indicates less effect of mixing; a larger DaM indicates that mixing will be a concern Estimates of mixing rates and mass transfer rates can be made from existing information for several reactor con gurations for both homogeneous and heterogeneous reactions These estimates combined with an estimate of the magnitude of the reaction rate can give a rough but useful approximation of the conditions under which mixing effects may be critical to the course of a reaction system and in scale-up This chapter is focused on the determination of those conditions.

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FIGURE 4.5 Control handles pull the line segment away from the straight line that would normally exist between them. The bottom path is a reversed S shape because the control handles are pulling in opposite directions. Anchor point Control handle

quality when taken alone; however, in the context of his other drawings and explanations it pointed toward sexual issues related to abuse and inadequacies. His next two renderings placed more pieces within the ensuing puzzle. In Figure 1.20 he drew his experiences of hurt. This rendering is completely symbolic and appears aggressively sexual in nature. He titled the image Love oasis ignorance. All marks with the exception of the linked circles are his experiences of hurt. The raindrop shape symbolized pain, while the word ignorance stood for lack of honor, which in turn stood for a lack of manhood. The linked circles were the love oasis. At the end of the session I asked the patient to place himself within the image; he is found as a small dot just inside the circled area. By Figure 1.21 he was again utilizing shapes within shapes and continued to use sexualized symbols (note the sun). However, on this day he was also verbally fantasizing about how we would set up house and how I would take care of him. With each statement and drawing, it was clear he was regressing into a state of dependency. The disintegration, produced by anxiety, was nding outlet in the safety and comfort of the familiar and a familiar person to take care of his needs. Yet the schizophrenic patient, fearful of closeness, tends to distort feelings and thereby concretize his or her thoughts. As Arieti (1955) has said, physical love is a concrete symbolization of what is really wanted: love and reassurance (p. 477). As a nal remark, in Figure 1.21 the patient is found on the far left with two

Several examples are included to illustrate reactor design problems and solutions for the major types of reacting systems Example 131 shows how mixing affects selectivity in various reactor con gurations..

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As you examine the different script steps in ScriptMaker, you ll notice that many of them include options that you can set. The options are individually explained

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Grid Computing Making the Global Infrastructure a Reality. Edited by F. Berman, A. Hey and G. Fox 2003 John Wiley & Sons, Ltd ISBN: 0-470-85319-0

The contents in a MySQL database are stored in tables. These tables are stored in databases that make up the MySQL system. The data stored in those tables is accessed using various statements and conditions, which are called queries. There are many statements that can be used in SQL queries.

Sub CopyRange() Range( A1:A5 ).Select Selection.Copy Range( B1 ).Select ActiveSheet.Paste Application.CutCopyMode = False End Sub

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From California AND FEMALE [the individual is a woman from California]

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