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made in Matsumura s extensive evaluation of anionic and cationic polymerized epoxy compounds shown in Scheme 13. Polymers with a molecular weight range of several hundreds to a few thousands, where X or Y may be carboxyl functionality and X or Y may be hydrogen or a substituent bearing a carboxyl functionality were evaluated. The extent of biodegradability, based on biochemical oxygen demand (BOD), is structure dependent. Water-soluble biodegradable polycarboxylates with an acetal weak link were the clever invention of Monsanto scientists [153] in their search for biodegradable detergent polymers. Clever science, however, was no match for economic necessity, and the polymers never reached commercial activity. The polymers are based on the anionic or cationic polymerization of glyoxylic esters at low temperature (molecular weight is inversely proportional to the polymerization temperature) and subsequent hydrolysis to the salt form of the polyacids. The salt is reasonably stable under basic conditions being a hemi acetal, or ketal when methylglyoxylic acid is used. Hydrolytic instability results from the pH drop a detergent polymer solution experiences as it leaves the alkaline laundry environment, pH ca. 10, and enters the sewage or groundwater environment where pH is close to neutral. The polymer is unstable and hydrolyzes to monomer, which rapidly biodegrades. The chemistry is outlined in Scheme 14 and is reported in many patents [153] and several publications [154, 155].

Since the early 1990s, laparoscopic (minimally invasive) surgery has increasingly replaced open operations in many elds of surgery and, because of the higher operative risks in obese patients, is widely used for gastric banding and other bariatric procedures. For laparoscopic surgery, a pneumoperitoneum is produced by insuf ating the peritoneal cavity with CO2, usually to a pressure of about 15 mm Hg.

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Figure 22.2 Impact of lifestyle improvement on the prevalence of obesity among children aged 11 12 and 15 16 years, who were found to be obese on screening in schools in Singapore. Data from the Trim and Fit programme (Toh, Cutter and Chew, 2002).

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DICOM RT objects include RT image, RT plan, RT structure set, RT dose, RT beams treatment record, RT Brachy treatment record, and RT summary record (Fig. 23.3, seven blue boxes).

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The most common reported side effects during these placebo-controlled trials of rimonabant were nausea (13% of cases), dizziness (9% of cases) and diarrhoea (7%); the frequency of these complaints was generally 2 3 times that with placebo. However, the greatest concern is the potential for neuropsychiatric side effects, notably anxiety and depression. The CB1 receptor in uences mood albeit in a complex fashion, with effects on anxiety and depression reported with both agonists and antagonists and so some impact on mental state was anticipated. Patients with depressive illness were largely excluded from studies of rimonabant, as with other obesity drug trials. A recent meta-analysis has shown that patients receiving rimonabant 20 mg daily were 2.5 times more likely to discontinue treatment because of depressive symptoms, and that anxiety scores (measured by the Hospital Anxiety and Depression Scale) were threefold higher, compared

15.4.1. Common Features The four interferometric objective setups that are typically used are based on the Michelson, Mirau, Linnik, and Fizeau interferometers. Schematics of these interferometric objectives are shown in Figure 15.25. A number of factors help determine the choice of best objective for a particular measurement. These factors include the level of magni cation or more precisely the numerical aperture required to both resolve the features and measure slopes and heights on the sample. At the same time a magni cation level that measures the entire area of interest on a sample needs to be chosen. This section rst describes various types of interferometric objectives and then examines the characteristics of different objective setups that determine which is best suited to a particular application. Types of Interferometric Objectives. The design of the interferometric objective is constrained by the mechanical limitations of the system. The four typical objectives differ in the ways that the beam is split into reference and object beams. In all but the Fizeau objective, the reference mirror is placed at the best focus of the objective to obtain best contrast fringes when the sample is in focus. In order to obtain best focus position, the object rst needs to be placed in focus, and then the reference mirror is moved to a position for which the best contrast fringes are obtained; this position also corresponds to best focus position. The best contrast fringes correspond to the zero optical path difference (OPD) between the reference mirror and the object position in the arms of the interferometer. Michelson interferometers (Fig.15.25(a)) are comprised of an objective, a beamsplitter and a separate reference surface. The microscope objective must have a long

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