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Eq (1450) This is a complex iterative step, consisting of a number of parts For a specific phase (liquid or vapor), application of Eq (1450) requires prior calculation of mixture properties 2 , /3, and I and partial properties qi The mixture properties come from solution of the equation of state, Eq (1438) or (1439), but this requires knowledge of q as calculated from qi values by Eq (1456) Moreover, Eq (1455) for qi includes the pure-species properties Zi and qi, which must therefore be determined first The sequence of calculations is as follows: 1 For each pure species as a liquid at the current value of P (initial estimate or adjusted value) determine Z i , pi, and 4 by Eqs (1433), (1432), and (662b) 2 For the liquid mixture at known T and composition calculate {Inyi} (assumed independent of P) For this liquid mixture at the current value of P , determine Z , I, q, and {qi}by iterative solution of Eqs (1439), (662b), (1455), and (1456) The process is implemented with an initial value, q = xiqi This allows solution of Eqs (1439) and (662b) for Z and I, which are used with Eq (1455) to yield values of qiEquation (1456) then provides a new value of q, and the process is repeated to convergence

public void validate(FacesContext context, UIComponent component, Object value)

Execute an SQL statement Execute an SQL statement and return a ResultSet object Execute an SQL statement that contains INSERT, UPDATE, or DELETE statements or DDL statements

When implementing a custom converter or validator, you may register them declaratively using converter or validator elements in the faces-configxml file, or you may register them dynamically at runtime using the API The converter and validator elements are direct children of the root faces-config element and must be the fully qualified Java class name of the class extending Converter or Validator, respectively See 15 for the facesconfigxml syntax for registering a Converter or Validator See 7 for any other converter or validator information

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3 Evaluate the set {$f) by Eq (1450) Values of Z,/3, and I for the liquid mixture are known from the preceding item 4 Repeat the calculations of item 2 for a liquid phase with the current vapor-phase composition (initial estimates or updated values) to determine q and { q i ) appropriate to the vapor phase This calculation is done with liquid-phase properties because the mixing rule for q is based on Eq (1454), which connects liquid-phase properties at the T and P of interest 5 Determine vapor-phase-mixture values for 2 , /3, and I by Eqs (1438), (1440), and (662b) at the current vapor composition 6 Evaluate the set (6;) by Eq (1450), with Z, /3, and I for the vapor-phase mixture from the preceding item Values for { K ; ) now come from Eq (1453) These allow calculation of { K i x i ) The constraint yi = 1 has not yet been imposed; most likely Ci Kixi # 1, and Eq (1452) is therefore not satisfied However, a new set of yi values is given by the normalizing equation:

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thus insuring that the yi values for the next iteration do sum to unity This new set { y i )is used to reevaluate I$:), { K i ) ,and { K i x i ) If Kixi has changed, { y i ) is again calculated and the sequence of calculations is repeated Iteration leads to a stable value of KixiIf this sum is not unity, the assumedpressure is incorrect, and must be adjusted Kixi < 1 , according to some rational scheme When Ci Kixi > 1 , P is too low; when P is too high The entire iterative procedure is then repeated with a new pressure P The last calculated values of yi are used for the initial estimate of { y i } The process continues until Ci Kixi = 1 A vast store of liquid-phase excess-property data for binary systems at temperatures near 30315 K (30 C) and somewhat higher is available in the literature Effective use of these data to extend G E correlations to higher temperatures is critical to the procedure considered here

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