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In this chapter you learned how to convert and transfer video from many popular formats and devices for playback on your PSP. As your video collection grows, your PSP can grow with you just buy more Memory Sticks or erase old movies from those sticks and replace them with others. Now you ll never be without your favorite shows and movies again!

The first vanadium-based metathesis catalyst (Me4Sn-V205 on alumina) was reported in 1993 8 The addition of alkyltin derivatives to some supported heterogeneous catalysts was shown to greatly increase catalytic activity 9,40 Most heterogeneous metathesis catalysts and some soluble homogeneous complexes, such as PhWCl 2 + AICl 3 or WCl 6 + AICI 3, do not require the use of a cocatalyst AICl 3 and other Lewis acids, whenever present, play an important role in catalyst systems by further increasing the activity of homogeneous catalysts Immobilized complexes anchored to the surface of oxide supports may serve as active metathesis catalysts In fact, Mo(CO)6 on alumina was reported in the first paper on metathesis by Banks and Baileyl Molybdenum and tungsten hexacarbonyls and alkylmolybdenum and alkyltungsten complexes have been studied most 6,24,26 Anchored organomolybdenum complexes are particularly effective catalysts, even at temperatures below O C; however, they quickly lose activity.

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41-43 Some catalysts, most notably W(CO)6 in a CCl 4 solution44,45 and systems based on molybdena,46 when irradiated, are effective in photoinduced metathesis In fact, a photoreduced silica-supported molybdena proved to be the most active olefin metathesis catalyst47 A special group of catalysts exerting great impacts on metathesis research, particularly on mechanistic studies, is carbene (alkylidene) complexes Only in 1972 was a stable rhodium metallocarbene intermediate complex isolated for the first time during a metathesis reaction 48 The complex also acted as a catalyst Since then many other preformed carbene complexes have been used as catalysts in olefin metathesis 7,14,30,49 In addition to carbenes of molybdenum,5o tungsten,51-54 and rhenium, 55 carbene complexes of niobium and tantalum56 also proved to be active catalysts Alkoxy group ligands have a marked effect on the activity of carbene complexes 49,54.

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A second option for creating Library items is the drag-and-drop method. Simply select an object or several objects on a page and drag them to the Library category (either the preview area or the Site list pane); release the mouse button to drop them in. You can drag any object into the Library panel: text, tables, images, Java applets, plugins, and/or ActiveX controls. Essentially, anything in the Document window that can be HTML code can be dragged to the Library. Similarly, as you might suspect, the reverse is true: Library items can be placed in your Web page by dragging them from the Library category and dropping them anywhere in the Document window.

As far as image resolution goes, at the beginning of the series, I created the characters at a very small size because we were delivering on the Web and needed to keep things small. Later, we found that it works best to create the characters at least 900 pixels high, so you have high-quality base art. Then you can scale down on export if needed. As a rough guide, I figured the characters should be big enough so that they were a little bigger than NTSC resolution (720x540 pixels). EXPORTING LAYERS FROM PHOTOSHOP Early in the series, before Flash supported the PNG format, we exported each layer from Photoshop as a JPG and cut out the backgrounds in Flash using the Eraser tool. This was a lot of work, but as a result we had vectors defining the edges of all our symbols that used bitmaps, giving a very clean edge even if the bitmap was low resolution. Now using much PNG is much simpler, and it supports 24-bit color with transparency and imports nicely into Flash.

Extending the ability to control the placement and size of windows, you can create windows offscreen and therefore (potentially) invisible to the user. This documented feature of FileMaker Pro 10 is useful for cases where you require a scripted procedure to undertake actions in another window so as to leave the user s environment undisturbed, while avoiding the visual discontinuity of a new window appearing and disappearing onscreen during the process.

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