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Aliphatic-type polymers are particularly prone to effects of nonuniform distribution of impurities since only the impurities are capable of absorbing terrestrial solar radiation Acceleration over real-time weathering is realized by continuous exposure to de ned conditions, uninterrupted by diurnal and seasonal cycles or variations in local weather conditions Further acceleration can be achieved by intensi cation of irradiance, temperature, and moisture However, the tests are only useful if they simulate the effects of outdoor exposure along with accelerating the rate of degradation The validity of the tests requires that the chemical and physical changes induced in materials and the stability rankings of materials are representative of the effects of the weather For this reason, the relative intensities of the stress factors that in uence the degradation process must be similar to those that exist in the natural environment so that the complex interactions of their effects are reproduced.
(4.17)
The single most important consideration when conducting laboratoryaccelerated weathering tests is the spectral power distribution (SPD) of the radiation source Both the absorption of light, which is a prerequisite to degradation, and bond breakage, the primary photochemical step following absorption of light, are wavelength dependent The wavelengths absorbed and the amount of radiation absorbed at each wavelength are dependent on the relation between the absorption properties of the material and the SPD of the light source Therefore, matching the SPD of terrestrial solar radiation, that is,.
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